The development of chiral organic materials with strong non-reciprocal chiroptical features may have major implications for cutting-edge technological applications. In this work, a new ad hoc synthesized chiral 1,4-diketo-3,6-dithienylpyrrolo[3,4-c]pyrrole dye, bearing two (S)-3,7-dimethyl-1-octyl alkyl chains on the lactam moieties and functionalized with two lateral 9-anthracenyl π-conjugated units, exhibited strong non-reciprocal chiroptical properties in thin films, with some important differences between samples prepared by drop casting and spin coating. A detailed study was performed to unravel the intimate structure-property relationship, involving computational analysis, different microscopy techniques and synchrotron radiation Mueller matrix polarimetry imaging (SR-MMPi) investigation. Through SR-MMPi, exploiting the highly collimated synchrotron radiation (SR) light of Diamond Light Source B23 beamline, we determined the size of the linear contributions responsible for the strong non-reciprocal features, and how they manifest in the various 2D chiral meso-domains.

Unravelling the origin of strong non-reciprocal chiroptical features in thin films of a chiral diketopyrrolo[3,4-c]pyrrole dye

Albano, Gianluigi
Primo
;
Bertuolo, Marco
Secondo
;
Zinna, Francesco;Taddeucci, Andrea;Pescitelli, Gennaro;Di Bari, Lorenzo
Ultimo
2025-01-01

Abstract

The development of chiral organic materials with strong non-reciprocal chiroptical features may have major implications for cutting-edge technological applications. In this work, a new ad hoc synthesized chiral 1,4-diketo-3,6-dithienylpyrrolo[3,4-c]pyrrole dye, bearing two (S)-3,7-dimethyl-1-octyl alkyl chains on the lactam moieties and functionalized with two lateral 9-anthracenyl π-conjugated units, exhibited strong non-reciprocal chiroptical properties in thin films, with some important differences between samples prepared by drop casting and spin coating. A detailed study was performed to unravel the intimate structure-property relationship, involving computational analysis, different microscopy techniques and synchrotron radiation Mueller matrix polarimetry imaging (SR-MMPi) investigation. Through SR-MMPi, exploiting the highly collimated synchrotron radiation (SR) light of Diamond Light Source B23 beamline, we determined the size of the linear contributions responsible for the strong non-reciprocal features, and how they manifest in the various 2D chiral meso-domains.
2025
Albano, Gianluigi; Bertuolo, Marco; Zinna, Francesco; Taddeucci, Andrea; Jávorfi, Tamás; Hussain, Rohanah; Farinola, Gianluca M.; Pescitelli, Gennaro;...espandi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/1304067
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