(py)Fe(CO)4(py = pyridine) is formed on carbonylation of [Fe(py)6][Fe4(CO)13], and the 56 electron tetranuclear cluster [(py)2FeFe(CO)4]2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.
Isolation of a Tetranuclear Iron Cluster Promoting CO2 Reduction and Intermediate to Iron Carbonyl Disproportionation
FACHINETTI, GIUSEPPE;FUNAIOLI, TIZIANA;
1987-01-01
Abstract
(py)Fe(CO)4(py = pyridine) is formed on carbonylation of [Fe(py)6][Fe4(CO)13], and the 56 electron tetranuclear cluster [(py)2FeFe(CO)4]2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.File in questo prodotto:
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