(py)Fe(CO)4(py = pyridine) is formed on carbonylation of [Fe(py)6][Fe4(CO)13], and the 56 electron tetranuclear cluster [(py)2FeFe(CO)4]2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.
|Autori:||FACHINETTI G; FOCHI G; FUNAIOLI T; ZANAZZI PF|
|Titolo:||Isolation of a Tetranuclear Iron Cluster Promoting CO2 Reduction and Intermediate to Iron Carbonyl Disproportionation|
|Anno del prodotto:||1987|
|Digital Object Identifier (DOI):||10.1039/c39870000089|
|Appare nelle tipologie:||1.1 Articolo in rivista|