(py)Fe(CO)4(py = pyridine) is formed on carbonylation of [Fe(py)6][Fe4(CO)13], and the 56 electron tetranuclear cluster [(py)2FeFe(CO)4]2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.

Isolation of a Tetranuclear Iron Cluster Promoting CO2 Reduction and Intermediate to Iron Carbonyl Disproportionation

FACHINETTI, GIUSEPPE;FUNAIOLI, TIZIANA;
1987

Abstract

(py)Fe(CO)4(py = pyridine) is formed on carbonylation of [Fe(py)6][Fe4(CO)13], and the 56 electron tetranuclear cluster [(py)2FeFe(CO)4]2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.
Fachinetti, Giuseppe; Fochi, G; Funaioli, Tiziana; Zanazzi, Pf
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/15252
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