The Co(bpy)32+ and Co(py)62+ complex cations form ion pairs with BPh4- counter-anions in pyridine solution. Excitation of the charge-transfer absorption band of the ion pair produces the corresponding Co(I) complexes, BPh4- being the electron source.
Photochemical Generation of Pyridine- and Polypyridine-Co(I) Complexes by Visible Light Irradiation of [Co(bpy)3](BPh4)2 and [Co(py)6](BPh4)2
FUNAIOLI, TIZIANA;FACHINETTI, GIUSEPPE
1990-01-01
Abstract
The Co(bpy)32+ and Co(py)62+ complex cations form ion pairs with BPh4- counter-anions in pyridine solution. Excitation of the charge-transfer absorption band of the ion pair produces the corresponding Co(I) complexes, BPh4- being the electron source.File in questo prodotto:
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