The VCD spectra of lanthanide chelates with two chiral ligands display conserved sequences of bands throughout the Ln series. Some compounds (Tm, Yb) feature increased bands and strongly improved signal-to-noise ratios, an effect we dub Lanthanide Induced VCD Enhancement (LIVE).
Shape-conserving enhancement of vibrational circular dichroism in lanthanide complexes
DI BARI, LORENZO;DI PIETRO, SEBASTIANO
2012-01-01
Abstract
The VCD spectra of lanthanide chelates with two chiral ligands display conserved sequences of bands throughout the Ln series. Some compounds (Tm, Yb) feature increased bands and strongly improved signal-to-noise ratios, an effect we dub Lanthanide Induced VCD Enhancement (LIVE).File in questo prodotto:
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