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EnglishVapor-liquid equilibria for dichloromethane or chlorobutane+a linear mono-, or diether (diethyl ether, dipropyl ether, methyl butyl ether, 1,2-dimethoxyethane,) or an acetal (diethoxymethane), were determined at 25°C by head-space gas chromatographic analysis of the vapor phase directly withdrawn from an equilibration apparatus. Excess Gibbs energies, GE, activity coefficients at infinite dilution, fi o as well as free energy of solvation, ΔGo, were evaluated for all the systems. A tentative approach is presented based either on an additivity scheme of surface interactions and scaled particle theory to calculate group contribution to the free energy of solvation.
| Autori interni: | |
| Autori: | LEPORI L.; MATTEOLI E.; TINE' M |
| Titolo: | Isothermal vapor-liquid equilibria of mixtures containing organic compounds. 7. Excess Gibbs energies of chloroalkane + oxaalkane mixtures at 298.15 K |
| Anno del prodotto: | 1991 |
| Digital Object Identifier (DOI): | 10.1021/je00004a018 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
http://hdl.handle.net/11568/17080
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