The reaction with water of acyldicarbonyl–Ru(II) complexes relevant to ruthenium catalysed ethene hydrocarbonylation with CO/H2O is shown to consist of a nucleophilic attack and to proceed via coordination of propionate and CO to the Ru(II) species.
Ethene hydroformylation with CO/H2O: nucleophilic attack by water on to a terminal CO of a Ru(II) acylcarbonyl complex
FACHINETTI, GIUSEPPE;FUNAIOLI, TIZIANA;MARCHETTI, FABIO
2005-01-01
Abstract
The reaction with water of acyldicarbonyl–Ru(II) complexes relevant to ruthenium catalysed ethene hydrocarbonylation with CO/H2O is shown to consist of a nucleophilic attack and to proceed via coordination of propionate and CO to the Ru(II) species.File in questo prodotto:
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