We discuss the possibility of implementing a switch based on a conformational change, consisting in a relative rotation of a molecule containing two benzene rings, functionalized with proper substituents. Contacts are simulated with three-atom gold clusters, which are connected to the rest of the molecule via a thiol group. Relative rotation of the two rings, induced by a transverse electric field, determines a variation of the height of the potential barrier separating them, due to the change in the amount of conjugation of the π orbitals. The action of such a barrier is evaluated by computing the shift of the electron density as a function of a longitudinal electric field.
Numerical investigation of a Molecular Switch based on conformational change, with the inclusion of contacts
CACELLI, IVO;MACUCCI, MASSIMO
2005-01-01
Abstract
We discuss the possibility of implementing a switch based on a conformational change, consisting in a relative rotation of a molecule containing two benzene rings, functionalized with proper substituents. Contacts are simulated with three-atom gold clusters, which are connected to the rest of the molecule via a thiol group. Relative rotation of the two rings, induced by a transverse electric field, determines a variation of the height of the potential barrier separating them, due to the change in the amount of conjugation of the π orbitals. The action of such a barrier is evaluated by computing the shift of the electron density as a function of a longitudinal electric field.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.