The two new diastereoisomeric chiral auxiliaries (aR,R)-29- Hydroxy-1,19-binaphthyl-2-yl [(3,5-dinitrobenzoyl)amino]- (phenyl)acetate and (aR,S)-29-Hydroxy-1,19-binaphthyl-2-yl [(3,5-dinitrobenzoyl)amino](phenyl)acetate have been synthesised and their efficiency as chiral solvating agents for the determination of the enantiomeric composition of amides and amines has been demonstrated. A conformational study of the two chiral solvating agents (CSAs) by means of NMR and CD spectroscopy is also presented.

3,5-Dinitrobenzoylphenylglycine analogues bearing the 1,1'-binaphthalene moiety. Synthesis, conformational study and application as chiral solvating agents

IULIANO, ANNA;UCCELLO BARRETTA, GLORIA;BALZANO, FEDERICA;SALVADORI, PIERO
2001

Abstract

The two new diastereoisomeric chiral auxiliaries (aR,R)-29- Hydroxy-1,19-binaphthyl-2-yl [(3,5-dinitrobenzoyl)amino]- (phenyl)acetate and (aR,S)-29-Hydroxy-1,19-binaphthyl-2-yl [(3,5-dinitrobenzoyl)amino](phenyl)acetate have been synthesised and their efficiency as chiral solvating agents for the determination of the enantiomeric composition of amides and amines has been demonstrated. A conformational study of the two chiral solvating agents (CSAs) by means of NMR and CD spectroscopy is also presented.
Iuliano, Anna; Bartalucci, D.; UCCELLO BARRETTA, Gloria; Balzano, Federica; Salvadori, Piero
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/184543
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 12
social impact