CINECA IRIS Institutional Research Information System
IRIS è la soluzione IT che facilita la raccolta e la gestione dei dati relativi alle attività e ai prodotti della ricerca. Fornisce a ricercatori, amministratori e valutatori gli strumenti per monitorare i risultati della ricerca, aumentarne la visibilità e allocare in modo efficace le risorse disponibili.
EnglishThe ruthenium(II) complex fac-[Ru(CO)2(H2O)3(C(O)C2H5)][CF3SO3] dissolved in aqueous tetrabutylammonium hydrogensulfate ([(CH3(CH2)3)4N][HSO4]) or sodium hydrogensulfate (NaHSO4) catalyzes the hydrocarboxylation of ethylene to propionic acid and additionally produces minor amounts of hydrocarbonylation products (diethyl ketone and propanal), under water-gas shift reaction conditions. This system is stable with a selectivity of 90% to propionic acid for high ethylene conversion. A turnover frequency of propionic acid, TOF(C2H5CO2H)/24 h=5x103 (TOF(C2H5CO2H)=([(moles of C2H5CO2H)/(moles of Ru)xrt)]x24 h) was achieved for Ru=7.45x10-4 mol, [(CH3(CH2)3)4N][HSO4]=80 g (2.36x10-2 mol); H2O=40 g (2.22 mol); CO=C2H4=20 g (total pressure=88 atm); T=150°C by a reaction time (rt) of 2.87 h. The countercation (sodium or tetrabutylammonium), the ruthenium concentration and the hydrogensulfate/ H2O ratio of the medium affect the catalytic reaction. A nonlinear dependence on total ruthenium concentration was shown. The data are discussed in terms of a potential catalytic cycle. Formation of propionic acid comes from hydrolysis, and formation of diethyl ketone and propanal comes from hydrogenolysis of the Ru-ketyl and Ru-acyl complexes, respectively.
| Autori interni: | |
| Autori: | PARDEY A J; RIVAS A B; LONGO C; FUNAIOLI T; FACHINETTI G |
| Titolo: | New Media in Homogeneous Catalysis: Wet Sodium or Tetrabutylammonium Hydrogensulfate Salts for Reppe Syntheses Catalyzed by a Ru(II) Carbonyl Complex |
| Anno del prodotto: | 2004 |
| Digital Object Identifier (DOI): | 10.1080/00928970410001721998 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
http://hdl.handle.net/11568/186942
Copyright © 2021