The ionic complex [PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+ containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by 195Pt NMR spectroscopy.
[PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+: A new and versatile ionic organometallic chiral derivatizing agent for the determination of the enantiomeric composition of chiral unsaturated compounds by 195Pt NMR spectroscopy
UCCELLO BARRETTA, GLORIA;LAZZARONI, RAFFAELLO;SALVADORI, PIERO
2000-01-01
Abstract
The ionic complex [PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+ containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by 195Pt NMR spectroscopy.File in questo prodotto:
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