The reaction of an ethene-coordinated Ru II complex with carboxylic acids is catalytic and produces equimolar amounts of ethane and 1,1′-diesters. The intermediate of the catalytic cycle is the alkyl complex [RuL n{CHCH 3(OC(O)C 2H 5)}- (CO) 2] (1-n)+ (L = RCOO -, CF 3SO 3 -), which was isolated in the dinuclear form.
Ethane and Ethylidene Dicarboxylates from the Ruthenium(II)-Catalyzed Disproportionative Addition of Carboxylic Acids to Ethene
FUNAIOLI, TIZIANA;MARCHETTI, FABIO;FACHINETTI, GIUSEPPE
2002
Abstract
The reaction of an ethene-coordinated Ru II complex with carboxylic acids is catalytic and produces equimolar amounts of ethane and 1,1′-diesters. The intermediate of the catalytic cycle is the alkyl complex [RuL n{CHCH 3(OC(O)C 2H 5)}- (CO) 2] (1-n)+ (L = RCOO -, CF 3SO 3 -), which was isolated in the dinuclear form.File in questo prodotto:
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