The reaction of an ethene-coordinated Ru II complex with carboxylic acids is catalytic and produces equimolar amounts of ethane and 1,1′-diesters. The intermediate of the catalytic cycle is the alkyl complex [RuL n{CHCH 3(OC(O)C 2H 5)}- (CO) 2] (1-n)+ (L = RCOO -, CF 3SO 3 -), which was isolated in the dinuclear form.

Ethane and Ethylidene Dicarboxylates from the Ruthenium(II)-Catalyzed Disproportionative Addition of Carboxylic Acids to Ethene

FUNAIOLI, TIZIANA;MARCHETTI, FABIO;FACHINETTI, GIUSEPPE
2002

Abstract

The reaction of an ethene-coordinated Ru II complex with carboxylic acids is catalytic and produces equimolar amounts of ethane and 1,1′-diesters. The intermediate of the catalytic cycle is the alkyl complex [RuL n{CHCH 3(OC(O)C 2H 5)}- (CO) 2] (1-n)+ (L = RCOO -, CF 3SO 3 -), which was isolated in the dinuclear form.
Funaioli, Tiziana; Marchetti, Fabio; Fachinetti, Giuseppe
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/204473
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