Lanthanide complexes of a pyridylphenylphosphinate ligand based on triazacyclononane form an isostructural series. The C-3-symmetric Delta and Lambda complexes of Eu and Tb are strongly emissive and can be resolved by chiral HPLC; the absolute configuration of each complex has been assigned using CD and CPL measurements.
Autori interni: | |
Autori: | Walton JW; Di Bari L; Parker D; Pescitelli G; Puschmann H; Yufit DS |
Titolo: | Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand |
Anno del prodotto: | 2011 |
Digital Object Identifier (DOI): | 10.1039/c1cc14904k |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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