Lanthanide complexes of a pyridylphenylphosphinate ligand based on triazacyclononane form an isostructural series. The C-3-symmetric Delta and Lambda complexes of Eu and Tb are strongly emissive and can be resolved by chiral HPLC; the absolute configuration of each complex has been assigned using CD and CPL measurements.

Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand

DI BARI, LORENZO;PESCITELLI, GENNARO;
2011

Abstract

Lanthanide complexes of a pyridylphenylphosphinate ligand based on triazacyclononane form an isostructural series. The C-3-symmetric Delta and Lambda complexes of Eu and Tb are strongly emissive and can be resolved by chiral HPLC; the absolute configuration of each complex has been assigned using CD and CPL measurements.
Walton, Jw; DI BARI, Lorenzo; Parker, D; Pescitelli, Gennaro; Puschmann, H; Yufit, Ds
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/204488
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