Consequences of Chirality on the Aggregation Behavior of Poly[2-methoxy-5-(2'-ethylhexyloxy)-p-phenylenevinylene] (MEH-PPV)

Poly[2-methoxy-5(2'-ethylhexoxy)-p-phenylenevinylene] (MEH-PPV) has been for the first time prepared and fully characterized in enantiopure (R) form. If the polymer molecular weight is sufficiently low, (R)-MEH-PPV assumes a helical supramolecular structure in the solution aggregates, with consequences on the tendency to aggregation and on the fluorescence quenching, both of which are reduced with respect to the racemic analogue.



Autori interni: 
PESCITELLI, GENNARO
DI BARI, LORENZO
DI PIETRO, SEBASTIANO
mostra contributor esterni 
Autori: Claudio Resta; Sebastiano Di Pietro; Maja Majeric Elenkov; Zdenko Hamersak; Gennaro Pescitelli; Lorenzo Di Bari
Titolo: Consequences of Chirality on the Aggregation Behavior of Poly[2-methoxy-5-(2'-ethylhexyloxy)-p-phenylenevinylene] (MEH-PPV)
Anno del prodotto: 2014
Digital Object Identifier (DOI): 10.1021/ma500921w
Appare nelle tipologie:1.1 Articolo in rivista

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Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11568/528667
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