Dimethyl- and dibenzyl-biscyclopentadienylzirconium(IV) react reversibly with carbon monoxide at atmospheric pressure giving the corresponding stable alkyl-acyl derivatives; the X-ray structure of the methyl derivatives shows the acyl group acting as a three-electron donor ligand.
Reversible Carbonylation of Dialkylbiscyclopentadienyl-zirconium(IV): Synthesis and Structure of pi-Acyl Derivatives of Zirconium and X-Ray Structure of Biscyclopentadienyl(pi-acetyl)methylzirconium.
FACHINETTI, GIUSEPPE;MARCHETTI, FABIO;MERLINO, STEFANO
1976-01-01
Abstract
Dimethyl- and dibenzyl-biscyclopentadienylzirconium(IV) react reversibly with carbon monoxide at atmospheric pressure giving the corresponding stable alkyl-acyl derivatives; the X-ray structure of the methyl derivatives shows the acyl group acting as a three-electron donor ligand.File in questo prodotto:
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