Reversible Carbonylation of Dialkylbiscyclopentadienyl-zirconium(IV): Synthesis and Structure of pi-Acyl Derivatives of Zirconium and X-Ray Structure of Biscyclopentadienyl(pi-acetyl)methylzirconium.

Fachinetti, Giuseppe; Floriani, C; Marchetti, Fabio; Merlino, Stefano

doi:10.1039/c39760000522

Dimethyl- and dibenzyl-biscyclopentadienylzirconium(IV) react reversibly with carbon monoxide at atmospheric pressure giving the corresponding stable alkyl-acyl derivatives; the X-ray structure of the methyl derivatives shows the acyl group acting as a three-electron donor ligand.

Autori:	FACHINETTI, GIUSEPPE FLORIANI C MARCHETTI, FABIO MERLINO, STEFANO mostra contributor esterni nascondi contributor esterni
Autori:	FACHINETTI G; FLORIANI C; MARCHETTI F; MERLINO S
Titolo:	Reversible Carbonylation of Dialkylbiscyclopentadienyl-zirconium(IV): Synthesis and Structure of pi-Acyl Derivatives of Zirconium and X-Ray Structure of Biscyclopentadienyl(pi-acetyl)methylzirconium.
Anno del prodotto:	1976
Digital Object Identifier (DOI):	10.1039/c39760000522
Appare nelle tipologie:	1.1 Articolo in rivista

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Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11568/58

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