Dimethyl- and dibenzyl-biscyclopentadienylzirconium(IV) react reversibly with carbon monoxide at atmospheric pressure giving the corresponding stable alkyl-acyl derivatives; the X-ray structure of the methyl derivatives shows the acyl group acting as a three-electron donor ligand.
Autori interni: | ||
Autori: | FACHINETTI G; FLORIANI C; MARCHETTI F; MERLINO S | |
Titolo: | Reversible Carbonylation of Dialkylbiscyclopentadienyl-zirconium(IV): Synthesis and Structure of pi-Acyl Derivatives of Zirconium and X-Ray Structure of Biscyclopentadienyl(pi-acetyl)methylzirconium. | |
Anno del prodotto: | 1976 | |
Digital Object Identifier (DOI): | 10.1039/c39760000522 | |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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