Reversible Carbonylation of Dialkylbiscyclopentadienyl-zirconium(IV): Synthesis and Structure of pi-Acyl Derivatives of Zirconium and X-Ray Structure of Biscyclopentadienyl(pi-acetyl)methylzirconium.

Dimethyl- and dibenzyl-biscyclopentadienylzirconium(IV) react reversibly with carbon monoxide at atmospheric pressure giving the corresponding stable alkyl-acyl derivatives; the X-ray structure of the methyl derivatives shows the acyl group acting as a three-electron donor ligand.



Autori interni: 
FACHINETTI, GIUSEPPE
MARCHETTI, FABIO
MERLINO, STEFANO
mostra contributor esterni 
Autori: FACHINETTI G; FLORIANI C; MARCHETTI F; MERLINO S
Titolo: Reversible Carbonylation of Dialkylbiscyclopentadienyl-zirconium(IV): Synthesis and Structure of pi-Acyl Derivatives of Zirconium and X-Ray Structure of Biscyclopentadienyl(pi-acetyl)methylzirconium.
Anno del prodotto: 1976
Digital Object Identifier (DOI): 10.1039/c39760000522
Appare nelle tipologie:1.1 Articolo in rivista

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http://hdl.handle.net/11568/58
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