The disproportionation of Co2(CO)8 in THF takes place only when water is present. Ion pairing interactions between Co2+ and Co(CO)4- are observed. The disproportionation is reversible at room temperature and under low PCO as a consequence of electron transfers between Co-I and CoII.

Cobalt(II)-Tetracarbonylcobaltate Ion Pairs: Electron Transfers Phenomena

FACHINETTI, GIUSEPPE;FUNAIOLI, TIZIANA
1984

Abstract

The disproportionation of Co2(CO)8 in THF takes place only when water is present. Ion pairing interactions between Co2+ and Co(CO)4- are observed. The disproportionation is reversible at room temperature and under low PCO as a consequence of electron transfers between Co-I and CoII.
Fachinetti, Giuseppe; DEL CIMA, F; Braca, G; Funaioli, Tiziana
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/7306
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