We designed a stereodynamic system, where the chirality of the analyte serves as a template for the helicity of the first coordination sphere of Co(ii). Giant VCD bands induced by Co(ii) allow the measurement of a completely significant and conclusive VCD spectrum in only a few seconds and/or on minute quantities of the analyte. This paves the way for the development of similar protocols, overcoming the limitations due to weak VCD signals for the assignment of absolute configurations.

Co(II)-induced giant vibrational CD provides a new design of methods for rapid and sensitive chirality recognition

PESCITELLI, GENNARO;DI BARI, LORENZO
2016-01-01

Abstract

We designed a stereodynamic system, where the chirality of the analyte serves as a template for the helicity of the first coordination sphere of Co(ii). Giant VCD bands induced by Co(ii) allow the measurement of a completely significant and conclusive VCD spectrum in only a few seconds and/or on minute quantities of the analyte. This paves the way for the development of similar protocols, overcoming the limitations due to weak VCD signals for the assignment of absolute configurations.
2016
Berardozzi, Roberto; Badetti, Elena; Carmo Dos Santos, Nadia Alessandra; Wurst, Klaus; Licini, Giulia; Pescitelli, Gennaro; Zonta, Cristiano; DI BARI, Lorenzo
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/803503
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