The employment of enantiomerically pure Schiff bases in manganese chemistry is revealed to be an excellent method to obtain chiral single-molecule magnets and has allowed the characterization of several pairs of enantiomers, for which the magnetic properties were investigated. The reported systems consist of MnIII-MnII-MnIII linear trimers or MnIII3 cations in a triangular arrangement including the first example of a μ3-Cl bridge in an isolated manganese triangle.

Trinuclear Complexes Derived from R/S Schiff Bases - Chiral Single-Molecule Magnets

DI BARI, LORENZO;Gorecki, Marcin
2016-01-01

Abstract

The employment of enantiomerically pure Schiff bases in manganese chemistry is revealed to be an excellent method to obtain chiral single-molecule magnets and has allowed the characterization of several pairs of enantiomers, for which the magnetic properties were investigated. The reported systems consist of MnIII-MnII-MnIII linear trimers or MnIII3 cations in a triangular arrangement including the first example of a μ3-Cl bridge in an isolated manganese triangle.
2016
Escuer, Albert; Mayans, Julia; Font Bardia, Merce; DI BARI, Lorenzo; Gorecki, Marcin
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/833970
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