Sfoglia per Autore
A Stable Palladium(I) Dimer with One 14e- Palladium Center and its Reversible Reaction with CS2, Affording a New Complex with a Planar Four-Coordinate Carbon
1995-01-01 Leoni, Piero; Pasquali, Marco; Giuseppe, Pieri; Alberto, Albinati; PAUL S., Pregosin; Heinz, Ruegger
Synthesis of mono-phosphido, mono-dppm bridged Pd(I) cationic dimers. Structure and fluxionality of [Pd-2(mu-P(t)Bu(2))(mu-dppm)(eta(1)-dppm),]CF3SO3 (dppm = bis-diphenylphosphinomethane)
1996-01-01 Leoni, Piero; Pasquali, Marco; Pieri, G; Englert, U.
CO-induced reductive elimination of P(t-Bu)2H from the platinum(II) dinuclear derivative Pt2[mu-P(t-Bu)2]2(H)2[P(t-Bu)2H]2, affording mononuclear platinum(0) or triangulo triplatinum(I,I,II) derivatives
1996-01-01 Leoni, Piero; Manetti, S; Pasquali, Marco; Albinati, A.
Proton Lability in Highly Hindered Dinuclear Palladium(I) mu-Phosphido-Secondary Phosphine Complexes. Crystal Structures of [Pd2(mu-PBut2)(PCy2H)3(CO)]BF4 and [Pd2(mu-PBut2)(PCy2H)2(mu,eta2,eta2-isoprene)]BF4
1996-01-01 Leoni, Piero; Pasquali, Marco; Milena, Sommovigo; Alberto, Albinati; PAUL S., Pregosin; H., Ruegger
Synthesis and reactivity of new phosphido-bridged di- and trinuclear platinum derivatives. Hydride abstraction from Pt-H bonds induced by oxidants
1996-01-01 Albinati, A.; Chiaradonna, G.; Klemens, P.; Leoni, Piero; Marchetti, Fabio; Manetti, S.; Pasquali, Marco
Synthesis and structure of Pd4(mu-P(t)Bu2)2(mu-CS2)(PPh3)2(I)2, a neutral palladium(I) derivative with a hexacoordinate carbon and a CS2 molecule bridging four palladium centers
1997-01-01 Leoni, Piero; Pasquali, Marco; Fadini, L; Albinati, A; Hofmann, P; Metz, M.
Synthesis, molecular and electronic structure of the first homoleptic complex of platinum with a secondary phosphine
1997-01-01 Leoni, Piero; Chiaradonna, G.; Pasquali, Marco; Marchetti, Fabio; Fortunelli, A.; Germano, G.
Synthesis of Palladium Sulfonium Ylides and the Structures of trans-[PdCl(CH2SR2)(PBut2H)2]X (X = CF3SO3, SR2 = Tetrahydrothiophene; X = PF6, R = Et)
1997-01-01 Leoni, Piero; Marchetti, Fabio; Paoletti, M.
Oxidant-induced hydride abstraction from [Pt(mu-P(t)Bu2)(H)(P(t)Bu2H))]2 yielding [Pt2(mu-P(t)Bu2)2(H)(P(t)Bu2H)2]C3(CN)5. Spectroscopic, crystallographic, and theoretical comparison of the structures of two ''Tautomers''
1998-01-01 Leoni, Piero; Pasquali, Marco; Fortunelli, A; Germano, G; Albinati, A.
Palladium(I) phosphido-bridged dinuclear derivatives with phosphite ligands
1998-01-01 Leoni, Piero; Papucci, S.; Pasquali, Marco
Stepwise substitution of terminal and bridging phosphines in [Pd2(mu-P(t)Bu2)(mu-P(t)Bu2H)(P(t)Bu2H)2]BF4 and the reactivity of [Pd2(mu-P(t)Bu2)(PPh3)3]BF4
1998-01-01 Leoni, Piero; Pieri, G.; Pasquali, Marco
Experimental and theoretical study of the kinetic and thermodynamic sites of protonation in (CO)Pt(mu-P(t)Bu2)2Pt(P(t)Bu2H)
1999-01-01 Leoni, Piero; Pasquali, Marco; Cittadini, V; Fortunelli, A; Selmi, M.
Palladium(I) phosphido-bridged dinuclear derivatives with both phosphine and amine ligands
1999-01-01 Leoni, Piero; Papucci, S.; Pasquali, Marco
Dinuclear phosphido-bridged derivatives of platinum(I). Synthesis and characterization of [Pt2(m-PtBu2)2(PtBu2H)(L)] [L = PtBu2R (R = H, Li, n-Heptyl), CO, h2-CS2]
1999-01-01 Leoni, Piero; Chiaradonna, G.; Pasquali, Marco; Marchetti, Fabio
Hemilabile phosphines by methyl acrylate insertion into the P-H bonds of palladium(I)-coordinated secondary phosphines. Labile anion (X = OTf) vs PO-chelate coordination (X = BF4) in Pd2(mu-PR2)(PR2R ')2(X) (R = Bu-t, R ' = CH2CH2COOMe; X = OTf, BF4)
2000-01-01 Leoni, Piero; Vichi, E; Lencioni, S; Pasquali, Marco; Chiarentin, E; Albinati, A.
The first examples of isonitrile insertion into a phosphido bridge and the crystal and molecular structures of [Pt2(mu-P(t)Bu2){mu,eta2-P(t)Bu-2)C(=NAr)}(CNAr)2] and [Pt{mu,eta2-P(t)Bu-2)C (NHAr)}(CNAr)]2(CF3SO3)2 (Ar = p-tolyl)
2000-01-01 Cristofani, S; Leoni, Piero; Pasquali, Marco; Eisentraeger, F; Albinati, A.
New dinuclear diphenylphosphido-bridged palladium(I) derivatives and the X-ray crystal and molecular structures of the mononuclear homoleptic diphenylphosphine complexes Pd(PPh2H)4 and [Pd(PPh2H)4](BF4)2,
2000-01-01 Leoni, Piero; Marchetti, Fabio; Papucci, S; Pasquali, Marco
Mechanism of Protonation of [Pt3(mu-PBu2)3(H)(CO)2],yielding the Hydride-Bridged [Pt3(mu-PBu2)2(mu-H)(PBu2H)(CO)2]OTf(Tf=CF3SO3),and the Spectroscopic and Theoretical Characterization of a Kinetic Intermediate
2001-01-01 A., Fortunelli; Leoni, Piero; Marchetti, Fabio; Pasquali, Marco; F., Sbrana; M., Selmi
The First Platinum Formyl, a Member of a Series of Hexanuclear Clusters Exhibiting a Rare Structure
2001-01-01 Leoni, Piero; Marchetti, Fabio; Marchetti, Lorella; Pasquali, Marco; Quaglierini, S.
Ligand Induced P-H Bond Formation vs Ligand Substitution, and a Comparison of the Reacivity of Two Isomers of [Pt2(m-PBut2)2(PBut2H)(CO)(H)]CF3SO3
2002-01-01 Cittadini, V; Leoni, Piero; Marchetti, Lorella; Pasquali, Marco; Albinati, A.
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